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  • pH-Metric Titration: The pH-metric method is a critical reference method because it can be used to measure all pKas between 2 and 12, with or without a UV chromophore, provided that the sample can be dissolved in water or water/co-solvent over the pH range of interest. While the pH-metric method is not fast enough for rapid screening, it provides a valuable backup for measuring samples without UV absorbance.

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